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Inductivity and Bridging in 2-Bicyclo[2.2.2]octyl Cations. Polar Effects, Part 11

✍ Scribed by Cyril A. Grob; Pawel Sawlewicz

Publisher: John Wiley and Sons
Year: 1984
Tongue: German
Weight: 616 KB
Volume: 67
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19840670729

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✦ Synopsis

Inductivity was defined as thc reaction constant p, in the equation log (klk,) = pluq, where k and k, are fmt-order rate consmiits for the substitutcd and unsubstituted tosylates, respectively, in 80% EtOH and u? i s the corresponding inductive substituent constant [3]. For recent reviews, see [2]. X-ray data [&I] show that the C(2)-C(7) distance (2.40 A) in 2 is actually shorter than the C(2)-C(6) distancc (2.50 A) in 1.

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