𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Inductively coupled plasma atomic emission spectrometric determination of cadmium in biological and environmental materials using electrothermal vaporization after in situ alkylation

✍ Scribed by Shiquan Tao; Takahiro Kumamaru

Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
537 KB
Volume
310
Category
Article
ISSN
0003-2670

No coin nor oath required. For personal study only.

✦ Synopsis

Trace amounts of cadmium in biological and environmental samples were determined by inductively coupled plasma atomic emission spectrometry by using an in situ alkylation/vaporization method. The alkylation and vaporization were carried out successively to suppress the decomposition of alkylcadmium species. By using ethylmagnesium bromide as alkylating agent, a detection limit of 11 pg of cadmium was obtained. The precision (R.S.D., n = 6) was 3.4% for 100 pg of cadmium. Compared to the conventional metal furnace electrothermal vaporization method, an obvious improvement in tolerance limit was obtained for all of the foreign ions examined. The contents of cadmium in some biological and environmental reference materials was determined by the proposed method and the results were in good agreement with the certified values.

📜 SIMILAR VOLUMES

Determination of Cadmium in Certified Re
Determination of Cadmium in Certified Reference Materials Using Solid Sampling Electrothermal Vaporization Inductively Coupled Plasma Mass Spectrometry Supplemented with Thermogravimetric Studies
✍ Gábor Galbács; Frank Vanhaecke; Luc Moens; Richard Dams 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 133 KB

The present study describes the application of solid sampling electrothermal vaporization inductively coupled plasma mass spectrometry (SS-ETV-ICP-MS) for the direct determination of Cd in five certified reference materials of plant, soil, and sediment origin. The work incorporates the optimization

A novel capillary microextraction on ord
A novel capillary microextraction on ordered mesoporous titania coating combined with electrothermal vaporization inductively coupled plasma mass spectrometry for the determination of V, Cr and Cu in environmental and biological samples
✍ Yiwei Wu; Bin Hu; Wenling Hu; Zucheng Jiang; Boyangzi Li 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 296 KB

## Abstract In this work, an ordered mesoporous titania film was introduced to coat a capillary by means of sol–gel technique. Sol–gel titania coating was developed for the preconcentration/separation of trace V, Cr and Cu by capillary microextraction (CME), and the adsorbed analytes were eluted fo