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Inductive and steric contributions of ortho-substituted pyridines to the process of inhibition of acid corrosion

✍ Scribed by Yu. G. Skrypnik; T. F. Doroshenko

Book ID
104809379
Publisher
Springer
Year
1996
Tongue
English
Weight
401 KB
Volume
31
Category
Article
ISSN
1573-885X

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Steric and electronic effects on the oxi
Steric and electronic effects on the oxidation of ortho-substituted benzhydrols by chromic acid
✍ D.G. Lee; M. Raptis πŸ“‚ Article πŸ“… 1973 πŸ› Elsevier Science 🌐 French βš– 483 KB

A study has been made of the oxidation of a number of substituted benzhydrols by chromic acid in aqueous acetic acid. The reaction rate constants are linearly proportional to the KR+ values of the alcohols. ortho-Substitution increases the rate of reaction and reduces the magnitude of the primary ki