Induction effects on IR-predissociation spectra of (SF6)2, (SiF4)2 and (SiH4)2

✍ Scribed by M. Snels; J. Reuss

• Publisher: Elsevier Science
• Year: 1987
• Tongue: English
• Weight: 444 KB
• Volume: 140
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(87)80483-9

✦ Synopsis

The observed difference in transition strength for ( SF6) 2, ( SiF,) 2 and ( SiH4) z IR-predissociation spectra is explained by induction effects (q&/R$)

which have to be included in the interaction Hamiltonian in addition to the dominant dipole-dipole term (&IR:z).