✦ LIBER ✦
Induced Fit Selection of a Barbiturate Receptor from a Dynamic Structural and Conformational/Configurational Library
✍ Scribed by Volker Berl; Ivan Huc; Jean-Marie Lehn; André DeCian; Jean Fischer
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 340 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-193X
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✦ Synopsis
The selection of the receptor presenting the strongest affinity addition of the barbiturate to an equilibrating mixture of hydrazone isomers leads to the quantitative shift towards a for a barbiturate substrate from a dynamic combinatorial library of constituents differing in structure and single species, 3, which presents highest complementarity to the substrate and yields the supramolecular entity 3:4. conformation/configuration is described. The gradual Induced-fit processes, or the specific structural adap- [a]