Induced conformational isomerization of 2-fluoro ethanol by selective infrared irradiation dm argon matrix

✍ Scribed by J. Pourcin; G. Davidovics; H. Bodot; L. Abouaf-Marguin; B. Gauthier-Roy

• Publisher: Elsevier Science
• Year: 1980
• Tongue: English
• Weight: 345 KB
• Volume: 74
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(80)85033-0

✦ Synopsis

The hght mduced lsomerlzatlon of the 2-fluoro ethanol Ge conformer IS studled usmg etther a broad band IR soumz, or an HF laser to excite the O-H stretchmg viiratlon spectral range. The products obtained followmg irradiation can be assened to other conformers, espenally the T, one the mcrease of its concentratron comcides with the decrease of that of the Gg conformer The fiomerlLauon mvolves mtramolccular energy transfer after a smgle photon absorption_