Individual solvation number of first-row transition metal(II) ions in solvent mixtures of N,N-dimethylformamide and N,N-dimethylacetamide—Solvation steric effect
✍ Scribed by Umebayashi, Yasuhiro; Matsumoto, Kai; Watanabe, Manabu; Ishiguro, Shin-ichi
- Book ID
- 118745933
- Publisher
- Royal Society of Chemistry
- Year
- 2001
- Tongue
- English
- Weight
- 222 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/B107342G
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📜 SIMILAR VOLUMES
The rate of the solvent substitution reaction, CoCl 3 S À +Cl À YCoCl 4 2À +S (S-solvent) has been studied by means of stopped flow spectrophotometry in dimethyl sulfoxide (DMSO) and N,N-dimethylformamide (DMF), and the rate constant k f , and the activation enthalpy D f H p and entropy D f S p have
## Abstract The solvation structure of magnesium, zinc(II), and alkaline earth metal ions in __N__,__N__‐dimethylformamide (DMF) and __N__,__N__‐dimethylacetamide (DMA), and their mixtures has been studied by means of Raman spectroscopy and DFT calculations. The solvation number is revealed to be 6