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Indium(III) Salt Promoted Intramolecular Addition of Allylsilanes to Unactivated Alkynes.

✍ Scribed by Katsukiyo Miura; Naoki Fujisawa; Sayaka Toyohara; Akira Hosomi


Publisher
John Wiley and Sons
Year
2006
Weight
29 KB
Volume
37
Category
Article
ISSN
0931-7597

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✍ JosΓ© Barluenga; MΓ³nica Trincado; Eduardo Rubio; JosΓ© M. GonzΓ‘lez πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 128 KB

Recently, organometallic transformations have been pursued with renewed interest to approach the elusive addition reaction of the NΓ€H bond across alkynes. [1] As a cleaner alternative to the use of metal-containing reagents and catalysts we have developed useful reactions for CΓ€C bond formation and