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Indium(III) chloride as an efficient, convenient catalyst for thioacetalization and its chemoselectivity

✍ Scribed by Sengodagounder Muthusamy; Srinivasarao Arulananda Babu; Chidambaram Gunanathan


Book ID
104211510
Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
84 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis


An efficient method for the preparation of 1,3-dithiolanes from aldehydes and ketones with 1,2-ethanedithiol in the presence of a catalytic amount of anhydrous indium(III) chloride is reported. A mild and highly chemoselective thioacetalization of carbonyl compounds using indium(III) chloride as the catalyst is also described. The desired products were obtained in 71-95% yield.


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ChemInform Abstract: Indium(III) Chlorid
✍ Sengodagounder Muthusamy; Srinivasarao Arulananda Babu; Chidambaram Gunanathan πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

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