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Indium(III) Bromide Catalyzed Chemoselective Dimerization of Vinylarenes.

✍ Scribed by Clovis Peppe; Ernesto Schulz Lang; Fabiano Molinos de Andrade; Lierson Borges de Castro


Book ID
101970233
Publisher
John Wiley and Sons
Year
2004
Weight
30 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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Mild, versatile, and chemoselective indi
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A series of acetonides (both terminal and internal isopropylidene acetals) have been deprotected under catalytic, neutral conditions to give their corresponding 1,2-diols. The reactions utilize indium(III) triflate in the presence of water and an organic solvent with mild microwave heating. Terminal