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Indium(III) Acetate-Catalyzed Intermolecular Radical Addition of Organic Iodides to Electron-Deficient Alkenes

โœ Scribed by Miura, Katsukiyo; Tomita, Mitsuru; Ichikawa, Junji; Hosomi, Akira


Book ID
118025114
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
70 KB
Volume
10
Category
Article
ISSN
1523-7060

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โœ Eun Lee; Chang Uk Hur ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 109 KB

Regio-and stereocontrolled synthesis of vinylstannanes was achieved by intermolecular addition reaction of a~-alkoxycarbonyl-fl-stannylvinyl radicals to activated alkenes. Under high dilution conditions cyclohexene derivatives were obtained via [2+2+2] radical annulation reaction.