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Indium-Mediated Reformatsky-Type Reaction of β-Aminovinyl Chlorodifluoromethyl Ketones with Heteroaryl Aldehydes.

✍ Scribed by Maurice Medebielle; Osamu Onomura; Robert Keirouz; Etsuji Okada; Hirokazu Yano; Terukazu Terauchi


Publisher
John Wiley and Sons
Year
2003
Weight
136 KB
Volume
34
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


📜 SIMILAR VOLUMES


Highly Substituted Homoallylvinylcyclopr
✍ Stephen M. Capps; Timothy P. Clarke; Jonathan P. H. Charmant; Henning A. F. Höpp 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 477 KB 👁 1 views

Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with α,β-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side