Indium-Mediated Reformatsky-Type Reaction of β-Aminovinyl Chlorodifluoromethyl Ketones with Heteroaryl Aldehydes.
✍ Scribed by Maurice Medebielle; Osamu Onomura; Robert Keirouz; Etsuji Okada; Hirokazu Yano; Terukazu Terauchi
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 136 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Allylindium reagents, prepared from excess allylic halide (Br or I) and indium metal, react with α,β-unsaturated ketones and aldehydes to give, after aerobic acidic workup, homoallyl-substituted vinylcyclopropanes. This process was explored and developed after a chance discovery arising from a side