Indium-Mediated Reductive Elimination of Halohydrins.
β Scribed by Sangwon Cho; Soyeon Kang; Gyochang Keum; Soon Bang Kang; So-Yeop Han; Youseung Kim
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 161 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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## Abstract A novel, efficient, and regioβ as well as diastereoselective conversion of nonβenolizable bicyclic Ξ±βdiketones into synthetically useful acyloins mediated by indium metal is described. The reduction is highly diastereoselective, leading exclusively to __endo__βacyloins (__endo__βhydroxy