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Indium-mediated one-pot reductive conversion of nitroarenes to N-arylacetamides

โœ Scribed by Byeong Hyo Kim; Rongbi Han; Fengyu Piao; Young Moo Jun; Woonphil Baik; Byung Min Lee

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
213 KB
Volume
44
Category
Article
ISSN
0040-4039

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Indium-HI-mediated one-pot reaction of 1
Indium-HI-mediated one-pot reaction of 1-(2-arylethynyl)-2-nitroarenes to 2-arylindoles
โœ Ji Sook Kim; Joon Hee Han; Jung June Lee; Young Moo Jun; Byung Min Lee; Byeong H ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 146 KB

While 1-(2-arylethynyl)-2-nitroarenes were reduced to 2-(2-arylethynyl)anilines in the presence of indium and InCl 3 in THF/H 2 O (v/ v = 5/1) at 50 ยฐC, 1-(2-arylethynyl)-2-nitroarenes were reductively cyclized to 2-arylindoles with good yields in the presence of indium and aqueous HI in benzene.