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Indium-mediated highly diastereoselective allenylation in aqueous medium: total synthesis of (+)-goniofufurone

โœ Scribed by Yi, Xiang-Hui; Meng, Yue; Li, Chao-Jun


Book ID
121700951
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
58 KB
Volume
4
Category
Article
ISSN
1359-7345

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A new method for the stereoselective synthesis of 1,3-amino alcohols based on the indium-mediated allylation of keto ester (R,S)-2 in aqueous media, resulting from shielding of one face by a remote substituent, was developed to be a useful method for acyclic stereocontrol in the absence of any obvio