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Indium mediated coupling of aldehydes with allyl bromides in aqueous media. the issue of regio- and diastereo-selectivity

โœ Scribed by Methvin B.Isaac; Tak-Hang Chan


Book ID
103400763
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
223 KB
Volume
36
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Indium-mediated allylation of carbonyl c
โœ Teck-Peng Loh; Zheng Yin; Hong-Yan Song; Kee-Leng Tan ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 315 KB

Anomalous syn-diastereoselectivity of indium-mediated coupling of aldehydes with bromides Z-3b and E-3b is reported. The reaction afforded high syn selectivity regardless of the allylic bromide geometry. Preliminary studies on the enantioselective indium-mediated allylation were attempted and found