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Indirect detection method for liquid chromatography based on electrogenerated luminol chemiluminescence

✍ Scribed by Yuwen Wang; Edward S. Yeung

Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
461 KB
Volume
266
Category
Article
ISSN
0003-2670

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✦ Synopsis

An mdtrect electrogenerated lummol chemdummescence detection method IS described, OH-, which IS a reactant m the lummol chenulummescence system, 1s produced by the reduction of hydrogen peroxide m a d c electrolysis flow cell Other reactants and supporting electrolyte are contamed m the eluent By the displacement of the reactants m the column the samples gave negatnre peaks The optmmm conditions for electrogenerated chemdummescence are discussed and a typical hqmd chromatogram I given The theoretical efficiency of the method was established The technique has detectlon llrmts of 0 011-O 058 gmol dependmg on sample type &ywor& Chenulummescence, Liquid chromatography, Indirect detection

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