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Indications of stereospecific loss of water from bicyclic ketones during chemical ionization mass spectrometry

✍ Scribed by Agosta, William C.; Bowen, David V.; Cormier, Russell A.; Field, Frank H.


Book ID
127240310
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
259 KB
Volume
39
Category
Article
ISSN
0022-3263

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In isobutane chemical ionization mass spectrometry benzyl alcohol exhibits ions at m/z 147 ('M+ 39') that arise by a loss of H 2 0 from [ M + C4Hy]+, i.e. 'M+ 57' complex ions. Electrophilic aromatic substitution of a proton at an ortho-position of neutral C6H5CH20H with [t-C4Hy]+ and, alternatively