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Indenyl- and Fluorenyl-Functionalized N -Heterocyclic Carbene Complexes of Titanium and Vanadium

✍ Scribed by Downing, Stephen P.; Danopoulos, Andreas A.

Book ID: 118175843
Publisher: American Chemical Society
Year: 2006
Tongue: English
Weight: 217 KB
Volume: 25
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om051017z

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## Abstract The novel phosphinidene complex [Cp\*(NHC)IrPMes\*] (**3**; NHC=1,3‐diisopropyl‐4,5‐dimethylimidazol‐2‐ylidene) was prepared in high yield from [Cp\*(NHC)IrCl~2~] (**2**) and [LiPHMes\*]**⋅**3 THF. It represents the first example of an NHC ligated transition metal phosphinidene complex