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Increased enantioselectivity in the presence of benzylamine in the heterogeneous hydrogenation of -unsaturated carboxylic acids

✍ Scribed by György Szöllősi; Taka-aki Hanaoka; Shu-ichi Niwa; Fujio Mizukami; Mihály Bartók

Book ID
113685559
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
121 KB
Volume
231
Category
Article
ISSN
0021-9517

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Enantioselective hydrogenation of exocyc
Enantioselective hydrogenation of exocyclic α,β-unsaturated ketones: Part II. Hydrogenation in the presence of (S)-proline
✍ Gabriella Fogassy; Antal Tungler; Albert Lévai; Gábor Tóth 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 74 KB

In the asymmetric synthesis of chiral compounds, the reduction of prochiral unsaturated reactants has a great importance. (S)-proline as a chiral auxiliary is used in the hydrogenations of exocyclic ␣,␤-unsaturated ketones with palladium on carbon catalysts, producing the corresponding saturated ke