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Incorporation of Chromium Carbenes in a Silica Matrix by Sol-Gel Processing: Application to Aminolysis of Alkoxycarbene Complexes

✍ Scribed by Simone Klapdohr; Karl Heinz Dötz; Wilfried Assenmacher; Wilfried Hoffbauer; Nicola Hüsing; Martin Nieger; Jürgen Pfeiffer; Michael Popall; Ulrich Schubert; Gregor Trimmel

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
398 KB
Volume
6
Category
Article
ISSN
0947-6539

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✦ Synopsis

Chromium carbene complexes have been immobilized in a silica matrix by sol ± gel processing based on the polycondensation of (trialkoxy)silylethylphosphane ligands and tetraalkoxysilanes. The microstructure of the material obtained depends on the gelation conditions. In situ gelation of alkoxy-or aminocarbene complexes with tetramethoxysilane (TMOS) affords mesoporous materials with a homogeneous distribution of the metal complex. The metal carbene moiety is accessible for small substrates as demonstrated for the aminolysis of the incorporated methoxy(phenyl)carbene complex which slows down with increasing bulk of the amine.

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