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In7Cl9—A New “Old” Compound in the System In-Cl

✍ Scribed by Prof. Dr. Horst Philipp Beck; Dipl.-Chem. Doris Wilhelm

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
319 KB
Volume
30
Category
Article
ISSN
0044-8249

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✦ Synopsis

Dedicated to Professor Hans Georg von Schnering on the occasion of his 60th birthday

The compounds In'Cl,['* 21 In,Cl, (In:In1"C1,),131 In& (In:Iny'C19),[41 and InCl, r55 6 ] have been unambiguously characterized in the system In-Cl. The phase diagram of the quasi-binary system InCl-InCl, has been investigated repeatedly by thermoanalytical methods.[,-' ' 1 The results indicated that, besides the above-mentioned compounds, a compound of composition In,CI, (InCl1.,,) or In,Cl, (In-Cll,z5) exists. However, this phase has still not been unambiguously characterized chemically or structurally. During our investigations of the system InCl-SnC1z,['ll we discovered a new binary mixed-valent phase of the In-Cl system, since, surprisingly, the redox reaction between In@ and SnZ@ led to the formation of In"' according to the reaction equa-

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