Photo-oxidation of tris(2,2'-bipyridine)
✍
Oleg V. Gerasimov; Valentin N. Parmon; Sergei V. Lymar
📂
Article
📅
1993
🏛
Elsevier Science
🌐
English
⚖ 962 KB
Thermal and photochemical oxidations of Fe(bpy)sz+ (bpy=2,2'-bipyridine) by the periodate anion IO,-in acidic aqueous solution were studied. For the thermal process, the rate-limiting step is monomolecular dissociation of the iron(D) complex preceding the fast oxidation by IO,-. Photo-oxidation of F