The bis-linking of tetrathiafulvalene (T
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C. Boulle; J.M. Rabreau; P. Hudhomme; M. Cariou; M. Jubault; A. Gorgues; J. Ordu
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Article
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1997
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Elsevier Science
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French
⚖ 134 KB
The bis-linking of a tetrathiafulvalene (ITF) to C60 is carried out by [4+2] Diels-Alder cycloaddition of C60 to the 2,3-dimethylene-TTF 2, this transient diene being generated by crown-6 mediated dibromine reductive elimination of the 2,3-bis(bromomethyl)'FYF 3. The C60-TTF target cycloadduct la is