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In the search of an electron transfer between π-donors and C60: the bis-linking of tetrathiafulvalene (TTF) to C60

✍ Scribed by P. Hudhomme; C. Boulle; J.M. Rabreau; M. Cariou; M. Jubault; A. Gorgues


Book ID
117540831
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
242 KB
Volume
94
Category
Article
ISSN
0379-6779

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The bis-linking of tetrathiafulvalene (T
✍ C. Boulle; J.M. Rabreau; P. Hudhomme; M. Cariou; M. Jubault; A. Gorgues; J. Ordu 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 134 KB

The bis-linking of a tetrathiafulvalene (ITF) to C60 is carried out by [4+2] Diels-Alder cycloaddition of C60 to the 2,3-dimethylene-TTF 2, this transient diene being generated by crown-6 mediated dibromine reductive elimination of the 2,3-bis(bromomethyl)'FYF 3. The C60-TTF target cycloadduct la is