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In Situ Synthesis of Polysulfides Covalently Bonded to Silica

✍ Scribed by Gabriel C. Ossenkamp; Tim Kemmitt; Jim H. Johnston


Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
145 KB
Volume
249
Category
Article
ISSN
0021-9797

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A novel chiral stationary phase (CSP) derived from the atropisomeric enantiomer S-3,3'-dicarboxy-2,2'-dihydroxy-l,l'-binaphthyl (S-DDBN) has been synthesized and its use for the separation of enantiomers demonstrated. The chiral selector is covalently bonded to amino-functionalized silica gel, thus