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In Situ Synthesis of Optically Active Poly( o -ethoxyaniline) in Organic Media and Its Chiroptical Properties

โœ Scribed by Su, Shi-Jian; Kuramoto, Noriyuki


Book ID
126140068
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
98 KB
Volume
13
Category
Article
ISSN
0897-4756

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The first rigid and sterically regular chiral poly[2,2 -bis(diphenylphosphino)-1,1 -binaphthyl] [poly(BINAP)] is synthesized. The application of this polymer ligand in asymmetric hydrogenations is examined. High enantioselectivity for the asymmetric hydrogenation of ketones is achieved. The catalyti