N and Cu cooperatively functionalized mesoporous resin and carbon materials with bicontinuous cubic structure (FDU-14) were obtained by a novel synthesis method. In this method, block copolymers were used as the templates as well as the precursors for the preparation of these modifying mesoporous materials. The CuC 2 O 4 in the channels of mesoporous FDU-14 resins was gotten by in situ oxidation of the templates in a catalytic redox system containing Cu 2þ , Al 3þ , NO 3 À , PO 4 3À , SO 4 2À ions. Simultaneously, the phenoleformaldehyde resin frameworks were in situ functionalized by the amine group resulting from the reduction of NO 3 À , leading to the formation of N and CuC 2 O 4 modified mesoporous FDU-14 resin materials. Its pyrolysis at the different temperatures resulted in the production of N and Cu cooperatively functionalized mesoporous FDU-14 resin and carbon materials. The structure and composition of these materials were characterized by the X-ray power diffraction, transmission electron microscopy, N 2 adsorptionedesorption analysis, X-ray photoelectron spectroscopy, infrared spectroscopy, thermogravimetry analysis, and inductive coupled plasma emission spectroscopy. The electrochemical measurement indicated that N and Cu cooperatively functionalized mesoporous FDU-14 carbon materials possessed the enhanced electrochemical hydrogen storage performance.