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In Situ Synthesis of Chlorinated Fullerenes by the High-Frequency Furnace Method

✍ Scribed by Andreas Mueller; Karolin Ziegler; Konstantin Yu. Amsharov; Martin Jansen


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
439 KB
Volume
2011
Category
Article
ISSN
1434-1948

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✦ Synopsis


Exohedrally chlorinated fullerenes have been synthesized by in situ chlorination using the high-frequency furnace method in the presence of carbon tetrachloride as reagent. In addition to the previously reported chlorinated non-IPR (isolated pentagon rule) fullerene cages of C 2n Cl 2m (n = 25, 27, 28, 30, 32 and 33, m = 2-6), a C 68 and various new higher fullerenes including C 2n Cl 2m with n = 36, 37 and 39 were [a]


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At high frequencies, one is interested in both the energy distribution and the energy #ow of connected vibrating structures. The prediction of time-and space-integrated energy quantity has been usually performed by the statistical energy analysis (SEA), whereas the vibration conduction analysis (VCA