## Abstract Water content in the membrane and the presence of liquid water in the catalyst layers (CL) and the gas diffusion layers (GDL) play a very important role in the performance of a PEM fuel cell. To study water transport in a PEM fuel cell, a two‐phase flow mathematical model is developed.
In situ Synchrotron X-ray Radiography Investigations of Water Transport in PEM Fuel Cells
✍ Scribed by I. Manke; C. Hartnig; N. Kardjilov; H. Riesemeier; J. Goebbels; R. Kuhn; P. Krüger; J. Banhart
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 862 KB
- Volume
- 10
- Category
- Article
- ISSN
- 1615-6846
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✦ Synopsis
Abstract
Water transport in an operating PEM fuel cell was investigated with synchrotron X‐ray radiography with a spatial resolution of 3 μm and a temporal resolution of 5 s. This method allows for the detection of water accumulations with less than 10 μm diameter. We demonstrate that synchrotron X‐ray imaging can dramatically expand the possibilities of imaging with high spatial and time resolution, especially as a complement to neutron radiography. Water transport processes from the first appearance of small water accumulations in the gas diffusion layer to their transport into the channel system were analysed in situ. Correlations between local effects such as water formation and operating conditions of the whole system, e.g. power variations, were found. A recently described eruptive water transport mechanism is analysed in detail.
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A novel in‐situ cell was designed to allow measurements during real fuel cell operation. Thus, potential and fuel dependent changes in the catalyst structure can be pursued in‐situ. The X‐ray absorption cell was built first in transmission geometry with an inherent graphite beam window, and spectra
## Abstract **Allgemeine Lösung**: In‐situ‐Synchrotron‐Röntgenbeugung in einem Reaktor, in den pulsförmig Eisenammoniumcitrat bei hohem Druck injiziert wird (siehe Bild), zeigt, dass Magnetitkeimbildung und ‐wachstum zeitlich getrennt ablaufen. Grammmengen kristalliner, reinphasiger, superparamagne