✦ LIBER ✦
In situ Raman spectra of the discharge products of calcium and lithium-anoded thionyl chloride cells — sulphur dioxide generation in oxyhalide systems
✍ Scribed by W.P. Hagan; D.G. Sargeant
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 640 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0378-7753
No coin nor oath required. For personal study only.
✦ Synopsis
A cell has been constructed that allows a caknun or hthmm-anoded oxyhahde cell of conventional composition to be analysed for catholyte-soluble &charge products usmg laser Raman spectroscopy Both cells showed the presence of sulphur dloxlde solvated by tluonyl chlonde Speaes of the type M(SOCl,)(SOJ'+(AlCl,),-could only be detected III cells havmg calcmm or l~thnun anodes w&h LuIlCI, as the supportmg electrolyte m 0uonyl chlonde Vapour pressure measurements of dwchargmg cells co-ed that Ca(AlCl& was less hkely to form a complex with sulphur &oxlde than the analogous hthnun salt