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In situ oxidation of a copper (I) complex to produce a hydroxy-bridged dinuclear copper (II) complex. Structural, magnetic and electrochemical properties

✍ Scribed by Liqin Chen; Laurence K. Thompson; John N. Bridson


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
634 KB
Volume
244
Category
Article
ISSN
0020-1693

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## Abstract A new end‐to‐end azido double‐bridged copper(II) complex [Cu~2~L~2~(N~3~)~2~] (1) was synthesized and characterized (L=1,1,1‐trifluoro‐7‐(dimethylamino)‐4‐methyl‐5‐aza‐3‐hepten‐2‐onato). Despite the rather long CuCu distance (5.105(1) Å), the magnetic interaction is ferromagnetic with