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In situ NMR identification of the intermediates and the reaction products in alcohols and hydrocarbons conversion on zeolites

✍ Scribed by A.G. Stepanov


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
432 KB
Volume
24
Category
Article
ISSN
0920-5861

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✦ Synopsis


In this paper the possibilities of 13C solid state NMR spectroscopy ( ~3C CP/MAS NMR) are demonstrated for identification of the intermediates and the reaction products in alcohols and hydrocarbons conversion on zeolites. As the particular examples the reactions of ethylene conversion and butyl alcohols dehydration on zeolite H-ZSM-5 are considered.


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## Abstract __Aqueous phase reforming of sorbitol over Pt supported on an alumina catalyst is investigated, in order to identify the intermediates involved in the transformation of the initial feed. Parameters such as the sorbitol feed rate and temperature are studied. To identify the intermediates