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In situ Generated Rhodium-Based Catalyst for Addition of Phenylboronic Acid to Aldehydes.

✍ Scribed by Murat Yigit; Ismail Oezdemir; Engin Cetinkaya; Bekir Cetinkaya

Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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In situ generated rhodium-based catalyst
In situ generated rhodium-based catalyst for addition of phenylboronic acid to aldehydes
✍ Murat Yiğit; İsmail Özdemir; Engin Çetinkaya; Bekir Çetinkaya 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 84 KB 👁 1 views

New 1, 4) as NHC precursors have been synthesized and characterized. These salts in combination with [RhCl(COD)] 2 provided active catalysts for the addition of phenylboronic acid to aldehydes under mild conditions. The in situ prepared three-component system [RhCl(COD)] 2 /imidazolinium salts (

Synthesis of silica-supported rhodium ca
Synthesis of silica-supported rhodium carbene complex as efficient catalyst for the addition of phenylboronic acid to aldehydes
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## Silica -supported catalytically active functional materials, such as the rhodium(I) carbene complex with 1-(triethoxysilylpropyl)-3-(2,4,6-trimethylbenzyl)imidazolidine-2-ylidine (L), were prepared using the sol-gel method. The complex (1; COD = 1,5-cyclooctadiene) RhCl(COD)[1-(triethoxysilylpr

In situ Preparation of Rhodium/N-Heteroc
In situ Preparation of Rhodium/N-Heterocyclic Carbene Complexes and Use for Addition of Arylboronic Acids to Aldehydes.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

In situ preparation of rhodium/n-heteroc
In situ preparation of rhodium/n-heterocyclic carbene complexes and use for addition of arylboronic acids to aldehydes
✍ Rafet Kilinçarslan; Engin Çetinkaya; Bekir Çetinkaya; Murat Yiǧit; İsmail Özdemi 📂 Article 📅 2007 🏛 Journal of Heterocyclic Chemistry 🌐 English ⚖ 324 KB 👁 1 views

## Abstract magnified image The __in situ__ prepared three component system [RhCl(COD)]~2~/imidazolidinium salts (**2, 4**) and KOBu^__t__^ catalyses the addition of phenylboronic acid to sterically hindered aldehydes affording the corresponding arylated secondary alcohols in good yields. Four nov