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In Situ Fourier Transform Infrared Spectroscopic Studies of Nitrite Reduction on Platinum Electrodes in Perchloric Acid

โœ Scribed by Bae, In Tae; Barbour, Rachael L.; Scherson, Daniel A.


Book ID
127255970
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
182 KB
Volume
69
Category
Article
ISSN
0003-2700

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Two reversible wavesare observed for the reduction of Ru(IV) on platinum electrodes. Each wave is the sum of two one-electron steps according to: 1st wllve Ru,(OH):: (IV)-Ru4(0H)$ (3,75)=Ru,(OH):+ (3.5) 2nd wave /wv-l Ru,(OH);+ (3,S)=Ru,(OH);+ (3.25)= Ru+(OH):+ (III) k, 4 stable Ru(II1) Potentials (