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In situ flow-injection monitoring of ammonia in landfill leachate

โœ Scribed by Martin J. Bloxham; Michael H. Depledge; Paul J. Worsfold


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
214 KB
Volume
9
Category
Article
ISSN
0895-7533

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โœฆ Synopsis


Aportable,12Vbattery-powered,automatedspectrophotometric field monitor has been developed that permits the continuous long-term recording of the total ammonia concentration in the surrounding aquatic environment. The flow-injection (FI)-based monitor incorporates a gas diffusion unit and an acceptor stream containing an acid-base indicator. The detection system utilizes a red solid-state light-emitting diode source and photodiode detector. Remote control and data processing are achieved by an inhouse-designed microcomputer system. The instrumentation was fully evaluated in the laboratory and was shown to operate unattended for periods of up to 1 week (analyzing every hour) before battery charging and reagent replacement were required. The precision and accuracy of the chemical monitor was examined by continuously analyzing a sample of a known ammonia concentration (80.0 mg L โ€ซ1ืžโ€ฌ NH 3 -N) at 60 minute intervals over a 7 day period (n โ€ซืกโ€ฌ 170). The calculated mean concentration was 79.0 mg L โ€ซ1ืžโ€ฌ (using 50 and 150 mg L โ€ซ1ืžโ€ฌ standards) with an RSD of 5.2%. The detection limit (3r) was determined as 2.5 mg L โ€ซ1ืžโ€ฌ . The feasibility of using the system in situ was demonstrated by a 2 week field trial in which the automated field monitor was successfully deployed at a landfill leachate lagoon. Data from the trial are presented, and the potential applications of the system in environmental management are discussed. แญง 1997


๐Ÿ“œ SIMILAR VOLUMES


Flow-injection determination of ammonia
โœ Celio Pasquini; Lourival Cardoso de Faria ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 580 KB

A flow injection/conductometric method is proposed for determing ammonia in solutions obtained from Kjeldahl digestion. The method is based on diffusion of ammonia through a PTFE membrane from an alkaline (NaOH/EDTA) medium to a deionized water stream. The change in conductance of the deionized wate