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In situ electrodeposition of catalysts for the electrocatalytic hydrogenation of organic molecules—I. The deposition of nickel

✍ Scribed by M.J. Lain; D. Pletcher


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
682 KB
Volume
32
Category
Article
ISSN
0013-4686

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✦ Synopsis


The electrodeposition of nickel onto vitreous carbon from acidic 90% C2 H s OH/10% H2 O containing tow Nit' concentrations is discussed. These unusual conditions have been selected to facilitate the design ofcathode surfaces which are active and reproducible for organic electrosynthesis . The objective is to deposit the catalyst in situ from the catholyte, hence producing it in its equilibrium state for the electrolysis conditions and also continuously renewing the surface.


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