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In-Phase Double Selective Excitation of Coupled Spin Systems Using Excitation Sculpting

✍ Scribed by Stéphane Bourg; Jean-Marc Nuzillard


Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
87 KB
Volume
133
Category
Article
ISSN
1090-7807

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✦ Synopsis


An experiment that excites exclusively coupled nuclei pairsis presented. It involves the biselective defocusing and refocusing of coupled transverse magnetization under double pulsed field gradient spin echo conditions. Application to the extraction of subspectra from crowded COSY spectra is presented, as well as a doubly selective version of the homonuclear J-resolved experiment. Copyright 1998 Academic Press.


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## Abstract Novel pulse sequences incorporating the double pulsed field gradient spin‐echo technique are presented that have particular use in identifying macromolecular bound water. The use of these sequences is illustrated using ribonuclease T~1~. Five amide protons cross‐relaxing with bound wate