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Improving the Performance of Methylalumoxane: A Facile and Efficient Method to Trap “Free” Trimethylaluminum

✍ Scribed by Busico, Vincenzo; Cipullo, Roberta; Cutillo, Francesco; Friederichs, Nic.; Ronca, Sara; Wang, Bing


Book ID
120532039
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
42 KB
Volume
125
Category
Article
ISSN
0002-7863

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Aryl-substituted epoxides undergo smooth rearrangement in the presence of 0.01-0.1 mol% Bi(OTf) 3 •xH 2 O. The rearrangement is regioselective with aryl-substituted epoxides, and products arise from cleavage of the benzylic C O bond. The highly catalytic nature of this method coupled with the fact t