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Improvements in the preparation and use of [tris(trimethylsilyl)methyl]lithium

โœ Scribed by Zakariah H. Aiube; Colin Eaborn

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
86 KB
Volume
269
Category
Article
ISSN
0022-328X

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ChemInform Abstract: Base-Free Tris(trim
ChemInform Abstract: Base-Free Tris(trimethylsilyl)methyl Derivatives of Lithium, Aluminum, Gallium, and Indium.
โœ F. SCHALLER; W. SCHWARZ; H.-D. HAUSEN; K. W. KLINKHAMMER; J. WEIDLEIN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 28 KB ๐Ÿ‘ 1 views

Base-Free Tris(trimethylsilyl)methyl Derivatives of Lithium, Aluminum, Gallium, and Indium. -Base-free Li-compound (II), prepared by an optimized trivial method, is used to synthesize metallanes (III). It reacts with one equivalent of AlCl3 to give metallate (IV), but reaction with one equivalent o