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Improvements in corrosion resistance, mechanical properties, and weldability of duplex austenitic/ferritic steels

✍ Scribed by Dr. C. A. Clark; P. Guha


Publisher
John Wiley and Sons
Year
1983
Tongue
German
Weight
492 KB
Volume
34
Category
Article
ISSN
0947-5117

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✦ Synopsis


The corrosion behaviour, toughness and weldability of duplex stainless steel can be improved by controlling the composition and austenite :ferrite ratio in the base metal and in the weld deposits. Addition of nitrogen is beneficial to ductility and restistance to pitting corrosion; the latter is also improved by increased chromium contents which stabilize the passive film. This effect is further enhanced by the addition of molybdenum which, however, should not exceed sigma phase at high temperatures. Copper in amounts up to 1.5% improves the resistance to marine environments; however, a certain upper limit should not be exceeded because of adverse effects on hot ductility. In view of the function of nickel concerning the austenite : ferrite ratio (which should be about 50 : 50) the nickel content should be appropriately selected and should be higher in the filter metal. Korrosionsverhalten, Festigkeit und SchweiDbarkeit von nichtrostenden Stahlen mit Duplex-Gefiige konnen durch entsprechende Zusammensetzung und Einstellung des Austenit : Ferrit-Verhaltnisses im Grundwerkstoff und im SchweiRgut verbessert werden. Zusatz von Stickstoff verbessert die Duktilitat und die Lochkorrosionsbestandigkeit; diese wird ebenfalls verbessert durch erhohte Chromgehalte, welche die Passivierungsschicht stabilisieren. Diese Wirkung wird noch verstarkt durch Zusatz von Molybdan, das jedoch bestimmte Grenzen nicht iiberschreiten darf, da sonst die Gefahr der Sigma-Phasen-Sprodigkeit bei hoheren Temperaturen besteht . Auch Kupfer in Mengen bis 13% verbessert die Korrosionsbestandigkeit besonders in Meerwasser, doch sollte wegen der abtraglichen Wirkung auf die Warmzahigkeit ein bestimmter Gehalt nicht iiberschritten werden. Wegen der wichtigen Rolle von Nickel fur das Austenit : Ferrit-Verhatnis (vorzugsweise 50 : 50) muB der Nickelgehalt entsprechend gewahlt werden und sollte im SchweiRgut etwas erhoht werden.


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