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Improvement on stability of square planar rhodium (I) complexes for carbonylation of methanol to acetic acid

✍ Scribed by Hua Jiang; Pinglai Pan; Guoqing Yuan; Xinzi Chen


Publisher
SP Science China Press
Year
1999
Tongue
English
Weight
276 KB
Volume
42
Category
Article
ISSN
1674-7291

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πŸ“œ SIMILAR VOLUMES


Square-Planar Carbonylchlororhodium(I) C
✍ Sylvain Burger; Bruno Therrien; Georg SΓΌss-Fink πŸ“‚ Article πŸ“… 2005 πŸ› John Wiley and Sons 🌐 German βš– 113 KB

## Abstract The rhodium(I) complexes __trans__‐[Rh(diphos)(CO)Cl] **7** (diphos=pbpb), **8** (diphos=nbpb), and **9** (diphos=cbpb) were synthesized (__Schemeβ€…4__) and used as catalysts for the carbonylation of MeOH to AcOH (__Schemeβ€…1__). The __trans__ coordination imposed by the rigid C‐spacer fr