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Improvement of Photoinduced Birefringence Properties of Optically Active Methacrylic Polymers through Copolymerization of Monomers Bearing Azoaromatic Moieties

✍ Scribed by Angiolini, Luigi; Benelli, Tiziana; Giorgini, Loris; Salatelli, Elisabetta; Bozio, Renato; Daurù, Alessandro; Pedron, Danilo


Book ID
123618748
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
176 KB
Volume
39
Category
Article
ISSN
0024-9297

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## Abstract The synthesis of a novel optically active methacrylic monomer containing in the side chain the (__S__)‐3‐hydroxy‐__N__‐phenyl pyrrolidine ring linked to a 4‐cyanophenylazocarbazole moiety [(__S__)‐**MCAPP**‐**C**] and of the analogous achiral monomer (**MCAPE‐C**) is described. Both the

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The synthesis of two novel optically active monomers containing 9-phenylcarbazole moieties, such as -MCPP], is described. Each monomer has been radically homopolymerized to afford the corresponding optically active polymeric derivatives, which have been fully characterized. Their spectroscopic, the

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Novel optically active polymethacrylates, namely poly[(S)-3-methacryloyloxy-1-(4-azobenzene)pyrrolidine] and poly[(S)-3-methacryloyloxy-1-(4Ј-nitro-4-azobenzene)pyrrolidine], have been synthesized by radical polymerization of the corresponding monomers, prepared in turn through a synthetic route pre

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## Abstract Novel optically active monomers such as __trans__‐(__S__)‐4‐(2‐methacryloylaminopropano‐ylamino)azobenzene, __trans__‐(__S__)‐4‐(2‐methacryloyloxypropanoylamino)azobenzene, and __trans__‐(__S__)‐4‐(2‐acryloylaminopropanoylamino)azobenzene have been prepared and homopolymerized by free r