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Improvement of chemical analysis of antibiotics : XIII. Systematic simultaneous analysis of residual tetracyclines in animal tissues using thin-layer and high-performance liquid chromatography

✍ Scribed by Yoshitomo Ikai; Hisao Oka; Norihisa Kawamura; Masuo Yamada; Ken-Ichi Harada; Makoto Suzuki


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
678 KB
Volume
411
Category
Article
ISSN
1873-3778

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✦ Synopsis


A simultaneous

analytical system for residual tetracycline antibiotics (TCs) in animal tissues including liver has been developed. This system consists of three methods using Baker 10 Cl8 clean-up followed by high-performance liquid chromatography (method A), thin-layer chromatography (TLC)-UV densitometry (method B) and TLC with spray reagents (method C). Methods A and B were established for the precise determination of TCs and method C for universal screening. The recoveries from beef liver fortified at the level of 1.0 ppm and their coefficients of variation were 60.5-83.3"/0 and 2.333.9% (method A) and 58.1-92.X% and 1.0 3.7% (method B), respectively. The detection limits in animal tissues were 0.01 ppm (method A) and 0.1 ppm (methods B and C). The time required for the analysis of four samples was 2.5-3 h with each method.