## Abstract For Abstract see ChemInform Abstract in Full Text.
Improved Stereospecific Syntheses of Novel 1-alkyl-3-benzoyl-4-hydroxy-4-phenylpiperidines
β Scribed by MOHAMMED JAFFAR; CHRISTOPHER UPTON
- Book ID
- 118110257
- Publisher
- Pharmaceutical Press
- Year
- 1996
- Tongue
- English
- Weight
- 227 KB
- Volume
- 48
- Category
- Article
- ISSN
- 2042-7158
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π SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(CΒ±C) = 0.002 A Γ R factor = 0.058 wR factor = 0.124 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
1-Benzoyl-2-methyl-3,4-dihydro-2-thianaphthalene (4a) underwent novel intermolecular 1,4-rearrangement in refluxing toluene to give an enol ether 5z while rearrangement of 2-phenyl derivative 4e proceeded intramolecularly in refluxing xylene to afford a 1,4-rearranged enol ether 5b. 5 the other hand