We have determined the surface energies (β₯ s ) of two liquid crystalline polyesters (Vectraβ’ A-950 [Hoechst Celanese, NJ] and Xydarβ’ [Amoco, GA]) and one polyesteramide (Vectraβ’ B-950 [Hoechst Celanese, NJ]) using contact angle techniques at room temperature. These LCPs were dissolved in bis-trifluo
Improved processing of thermotropic liquid crystalline polyesters
β Scribed by Ronald N. Demartino
- Publisher
- John Wiley and Sons
- Year
- 1983
- Tongue
- English
- Weight
- 312 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
A series of thermotropic liquid crystalline polyesters based on p-hydroxybenzoic acid, terephthalic: acid, 2,6-dihydroxynaphthalene and containing small amounts of either Bisphenol A, 2,7-dihydroxynaphthalene, or polyethylene terephthalate (PET) as comonomers were prepared. The latter three materials were investigated as a means of lowering the spinning temperature of the base polymer without sacrificing properties. Samples containing 1-2.5% Bisphenol A or 2.5-5% 2,7-dihydroxynaphthalene retained most of the properties (modulus fell slightly), but spinning temperature re-. duction was minimal. Polymers containing 2.5-5% P E T retained full properties a t spinning tern-. peratures 60-80Β°C below the control.
π SIMILAR VOLUMES
## Abstract Cholesteric liquid crystalline polyesters were successfully synthesized from isosorbide, methyl hydroquinone, and isophthaloyl chloride. Homo/copolyesters were synthesized by the solution polycondensation method, for which a mild organic base such as pyridine was employed. Inherent visc
This paper is concerned with properties and processing performance of two thermotropic liquid crystalline polymers (TLCPs) produced by DuPont (HX6000 and HX8000) with widely varying melting points and blends of these two TLCPs. This work was carried out in an effort to develop a TLCP suitable for ge