Aromatic and aliphatic aldehydes and ketones react with AlCl 3 ยฑZn in acetonitrile to yield oleยฎns in good yield
Improved procedures for the reductive coupling of carbonyls to olefins and for the reduction of diols to olefins
โ Scribed by McMurry, John E.; Fleming, Michael P.
- Book ID
- 120250796
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 259 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
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An improved procedure for the stereospecific synthesis of olefhm from 1,2-dials via the corresponding thionocarbonate is described. The introduction of the versatile oleflnic function by &oxygenation of a 1,2-diol is a useful technique in organic synthesis. Although numerous procedures have appeare