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Improved method for fitting falloff data

✍ Scribed by James S. Poole; Robert G. Gilbert

Publisher
John Wiley and Sons
Year
1994
Tongue
English
Weight
602 KB
Volume
26
Category
Article
ISSN
0538-8066

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✦ Synopsis

An extension of the dimensionless treatment of Troe is developed for fitting falloff data from unimolecular and recombination reactions. This method using dimensionless parametrizations derived from accurate numerical solutions of the master equation for system with any type of activated complex and energy transfer probability distribution, is as easily implemented as Troe's method, and allows global fitting of an entire set of pressure-and temperature-dependent rate coefficients.

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