Improved corrosion resistance of cast carbon steel in sulphur oxides by alonizing

✍ Scribed by Dr. M. Holtzer; M. Sc. Eng. Z. Dzioba

• Publisher: John Wiley and Sons
• Year: 1992
• Tongue: German
• Weight: 476 KB
• Volume: 43
• Category: Article
• ISSN: 0947-5117
• DOI: 10.1002/maco.19920430206

✦ Synopsis

Abstract

The results of studies on the Alonizing of cast carbon steel and of testing the corrosion resistance of this cast steel in an atmosphere containing 5 to 6% SO~2~ + 50% SO~3~ at 853 K are described and compared with the results obtained with unalonized cast carbon steel and high‐alloy 23Cr‐8Ni‐2Mo cast steel. The duration of the corrosion tests was 336 hours. The aluminium diffusion layer on cast carbon steel was obtained by holding the specimens in a mixture containing 99% of powdered Fe‐Al and 1% of NH~4~Cl at 1323 ± 20 K. The holding time was 10 and 20 hours, respectively.

The aluminium layer formed on the cast carbon steel was examined by optical microscopy and an X‐ray microanalysis. After Alonizing for 10 h the layer had reached a thickness of 950 μm, and contained up to 35% Al.

In a mixture of sulphur oxides corrosion rate of the alonized cast carbon steel was by about 600 times lower than that of the unalonized cast carbon steel, and by about 50 times lower than that of the 23Cr‐8Ni‐2Mo cast steel.