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Impregnation of ammine aqua cobalt(III) complexes on η-Al2O3 investigated by NIR FT-Raman spectroscopy

✍ Scribed by Yuying Chen; Jens Hyldtoft; Claus J.H. Jacobsen; Daniel H. Christensen; Ole Faurskov Nielsen


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
796 KB
Volume
50
Category
Article
ISSN
1386-1425

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✦ Synopsis


Ah&act-The impregnation of ammine aqua cobalt(W) complexes on r]-A&O, was investigated by NIR FT-Raman spectroscopy and in a few cases by UV-vis spectroscopy and X-ray powder diffraction. The cobalt(II1) impregnated alumina samples were prepared from different precursors using different impregnation methods. The observed Raman bands for the impregnated alumina around 522-537 cm-' were tentatively assigned to the vibrational modes for the Co-OAl or Co-O(H)AI bonds (Al = aluminium atom on AI,OJ surface).

Keynor& FT-Raman, NIR, ammine aqua cobalt(II1) complexes, t]-A1203,