Importance of the concept of bond and binding in the physical chemistry of solids
β Scribed by L. Lafourcade
- Publisher
- John Wiley and Sons
- Year
- 1981
- Tongue
- English
- Weight
- 418 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
β¦ Synopsis
Abstract
The nature of problems connected with binding which arise in the everyday work of experimental physicists and material scientists is illustrated by reference to two different experimental studies. (i) Sliding in crystals of group V elements is found to take place not only along planes cutting the quasimetallic bonds, but also along planes apparently cutting their βcovalentβ bonds, thus suggesting that a more elaborate picture of the two types of bonds and of their interrelation is necessary. (ii) The physisorption of linear pentatriacontane on alkali chlorides indicates alignment of the paraffin molecules along the [110] directions. This may be associated with polarization of methylene groups by ions in the substrate. This hypothesis must be substantiated by suitable quantumβtheoretical calculations, which in turn must be based on an adequate description of the adsorption bond.
π SIMILAR VOLUMES
This Book Is A Basic Reference Providing Concise, Accurate Definitions Of The Key Terms And Concepts Of Organic Chemistry. Not Simply A Listing Of Organic Compounds, Structures, And Nomenclatures, The Book Is Organized Into Topical Chapters In Which Related Terms And Concepts Appear In Close Proximi
This Book Is A Basic Reference Providing Concise, Accurate Definitions Of The Key Terms And Concepts Of Organic Chemistry. Not Simply A Listing Of Organic Compounds, Structures, And Nomenclatures, The Book Is Organized Into Topical Chapters In Which Related Terms And Concepts Appear In Close Proximi